magnetite layer formation in boiler

Metal surface passivation in an operating boiler is a slow controlled corrosion process taking place on a continuous basis Under design operating conditions internal boiler corrosion leads to the formation of magnetite on the metal surfaces with the release of hydrogen Well unhydrated crystallized magnetite forms a dense layer However at increased rates the rate of bubble formation may exceed the flow of rinsing water and at higher still rate a stable film may occur with corrosion concentrations at the edge of this blanket The magnetite layer is then attacked leading to metal loss The area under the film may be relatively intact

Marine education: CORROSION FOUND IN BOILER AND

However at increased rates the rate of bubble formation may exceed the flow of rinsing water and at higher still rate a stable film may occur with corrosion concentrations at the edge of this blanket The magnetite layer is then attacked leading to metal loss The area under the film may be relatively intact

14 09 2015IJIRST journal Published some good research work Paper Title:- Impact of Boiler Water Chemistry on Waterside Tube Failures Abstract: This paper emphasis on the study of typical premature failure of water wall tubes of two thermal power plant boiler of same capacity (250 MW) and same operational parameter but with different boiler water chemistry

Our scale corrosion inhibitors provide optimum alkalinity which is extremely important for efficient boiler water treatment and helps in correct precipitation of hardness salts neutralization of acid conditions control of magnesium and calcium salts and passivation by a magnetite layer

Both high and low pH can cause corrosion in boiler In acidic range the protective layer of magnetite is not able to form and it cause corrosion In very high pH range the protective layer of magnetite breaks down and this leads to caustic corrosion For corrosion prevention maintaining proper pH

Magnetite Film Formation on Boiler Tubes 3 Fe + 4 H 2O → Fe 3 O 4 + 4 H 2 0 2 4 6 8 10 12 14 2 0 1 5 1 0 0 5 0 0-0 5-1 0 Fe 1 000E+00 1 112E+02 Above ~ 230oC Magnetite Film Forms on Carbon Steel in Slightly Alkaline Oxygen-free Water XRD of SA 210 Carbon Steel Grained Layer Inner Tube Surface Normal Boiler Tube Microstructure Middle

surfaces of the boiler proper tubes from the Formation of

hours) Then they discussed a mechanism of formation of a compact layer protecting a steel surface against excessive oxidation under combustion gases Practical implications: The layer on the tubes with small losses of wall thickness are characterized by the following properties: good compactness very good adhesion to the metallic base low amount of sulfur especially in magnetite no

Iron can enter the boiler as soluble ferrous ions and insoluble ferrous and ferric hydroxides or oxides Oxygen-free alkaline boiler water converts iron to magnetite Fe 3 O 4 Migratory magnetite deposits on the protective layer and is normally gray to black in color Copper Oxide Formation

Both high and low pH can cause corrosion in boiler In acidic range the protective layer of magnetite is not able to form and it cause corrosion In very high pH range the protective layer of magnetite breaks down and this leads to caustic corrosion For corrosion prevention maintaining proper pH

The water required for boiler feed purposes i e for steam generation should be of very high quality and thus requires a lot of treatment Untreated waters containing impurities may lead to the following problems in boilers: Scale and sludge formation Boiler to reduce oxidation and to support the forming of a stable layer of magnetite

process forming of magnetite and hematite layer Magnetite formation within a steam boiler system is costly to between the tube and the Magnetite layer will fracture the scale makeup water demand cost of processing water cost of removing weakly magnetic species such as Hematite

Corrosion control is effective – Protective Magnetite layer formed on steel surface and showing good corrosion protection ASE TUDY 003/Mal_01-R1 Location 3Ton Fire Tube boiler water treatment using BacComber ULF Descaler SINGAPORE 010/Sin_07 History Chemical Treatment BacComber ULF Treatment 2002 Inspection 01

of a thin passive layer of iron on the internal drum surfaces referred to as magnetite Metal passivation is a critical process that occurs and provides protec-tion of the Yankee dryer system Passivation is the formation of an insoluble nonporous protective oxide on a metal surface Cast iron and steel will self-

1 2 / GE / April 3 2015 Magnetite Layer A protected layer of magnetite (Fe3O4) is formed on water touched metal surfaces in the steam generator Magnetite layer acts as a coherent media that stops further corrosion of the base metal Magnetite is the combination of FeO and Fe2O3 Oxygen scavenger Carbohydrazide converted to Hydrazine at temperature 135 degree C Hydrazine passivate oxidized

Boiler water related problems I

A well maintained and treated boiler water system will promote the formation of a black magnetite iron oxide coating inside the boiler which protects it from corrosion However incorrect pH control and dissolved gases in the water will destroy its coating leaving the system susceptible to corrosion Above and below a pH of 10 the

commissioning a new boiler to accelerate the formation of this protective layer An additional benefit comes from the fact that the film acts to improve thermal transfer efficiency Magnetite Formation To fully understand the benefit of Magnetite let's first look at how Magnetite is formed within a steam boiler system Magnetite is a product

mpy During the boiler drainage no sign of any rust formation in the discharged water was observed The control ER probe showed heavy rust formation on its surface while the 100 mg/L VCI ER probe showed a thin layer of black magnetite and relatively clean surfaces Comparison of these inter-

2006 A It is always advisable to use passivation for boiler Or else when using water in the boilers it is generally agreed to add inhibitors which will form a protective layer on the inner side of the boiler and thus prevent further corrosion

1 Mw boiler for corrosion experiments at KEMA (the Netherlands) In order to be able to include the different dynamic factors in the general investigation of steam generation corrosion -heat flux two-phase flow of the water-steam mixture and formation of deposits -N V KEMA has an experimental boiler installation (Fig 1)

The boiler tubes of X20CrMoV12 1 used in fossil-fired power plants were obtained and analyzed for the effect of water treatment on the steam corrosion-induced oxide scale in an effort to better understand the oxide formation mechanism as well as pertinent method of maintenance and lifetime extension

Magnetite Film Formation on Boiler Tubes 3 Fe + 4 H 2O → Fe 3 O 4 + 4 H 2 0 2 4 6 8 10 12 14 2 0 1 5 1 0 0 5 0 0-0 5-1 0 Fe 1 000E+00 1 112E+02 Above ~ 230oC Magnetite Film Forms on Carbon Steel in Slightly Alkaline Oxygen-free Water XRD of SA 210 Carbon Steel Grained Layer Inner Tube Surface Normal Boiler Tube Microstructure Middle

as well as formation of protective oxides (i e magnetite etc ) Performance in the Field HYDROGUARD I-15 has performed very well in the field For example one plant wanted to replace hydrazine due to toxicity concerns This plant operated a coal-fired boiler at ~ 54 bar (800 psig) for power generation (turbines) and process heating with

scale and sludge formation in boilers ppt Corrosion inhibitors and dispersants to control scale and sludge formation Extreme Boiler Scale buildup Sludge can also be treated by two approaches It disperses the sludge throughout the feed water so sludge does not form To support the formation of a stable layer of magnetite on the water-side

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