ethylbenzene hazards

Ethylbenzene is used mostly as a gasoline and aviation fuel additive It may also be present in consumer products such as paints inks plastics and pesticides • Xylene is a member of the BTEX group of pollutants Ortho-xylene is the only naturally-occurring form of xylene the other two forms are man-made Xylenes are colourless liquids used in gasoline and as a solvent in printing rubber Acute hazards to the aquatic environment 74 4 % Chronic hazards to the aquatic environment 100 % Hazard Symbol: Label Elements Version: 2 0 Revision Date: 12/02/2016 800000030099 3/30 Signal Word: Warning Hazard Statement: Flammable liquid and vapor Causes serious eye irritation Suspected of causing cancer Precautionary Statements Prevention: Keep away from heat hot surfaces sparks

Xylene (mixture of isomers) anhydrous (max 0 005% H₂O

In view of the hazards of certain chemicals and apparatus the customer must ensure that the products purchased are in a safe condition and that a safe system of work is in place taking into account all available information None of the products sold are intended for

IATA: Ethylbenzene 14 3 Transport hazard class(es) ADR/RID: 3 14 4 Packaging group ADR/RID: II 14 5 Environmental hazards ADR/RID: no 14 6 Special precautions for user No data available SECTION 15: Regulatory information IMDG: 1175 IATA: 1175 IMDG: 3 IATA: 3 IMDG: II IATA: II IMDG Marine pollutant: no IATA: no This safety datasheet complies with the requirements of Regulation (EC) No

Formaldehyde: Authoritative entities on chemical hazards agree that formaldehyde is a known human carcinogen Our own product testing revealed the presence of two chemicals ethylbenzene and vinyl acetate in products marketed to kids These ingredients were not listed on labels leading us to suspect they may have been used in fragrance These chemicals are not on the IFRA list of fragrance

specific hazards safe work practices and emergency procedures for fire evacuation and natural disaster as appropriate Any site-specific hazard or color coding in use should be thoroughly reviewed as part of orientation training Visitor Orientation • If visitors to the site can gain access to areas where hazardous conditions or substances may be present a visitor orientation and

Ethylbenzene 100-41-4 202-849-4 0268 0 5% HAZARD CLASSIFICATION: [F] Flammable [Xn] Harmful RISK PHRASES: R11 R20 Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0 1% for carcinogens reproductive toxins or respiratory sensitizers) NOTE: ALL WHMIS required information is included in appropriate sections basedon the ANSI Z400 12010

SAFETY DATA SHEET

ETHYLBENZENE (CAS TWA 20 ppm 100-41-4) US NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-PROPANONE (CAS TWA 590 mg/m3 67-64-1) 250 ppm BENZENE DIMETHYL STEL 655 mg/m3 (CAS 1330-20-7) 150 ppm TWA 435 mg/m3 100 ppm Carbon Dioxide (CAS STEL 54000 mg/m3 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm ETHYLBENZENE

100-41-4 Ethylbenzene {Ethylbenzol Phenylethane} 10 0 -30 0 % Additional Chemical Ethylbenzene is a component of Xylene Information Licensed to W M Barr and Company GHS format Revision: 09/04/2014 Printed: 10/06/2014 Page: 3 Jasco Xylol Xylene SAFETY DATA SHEET Supersedes Revision: 06/16/2011 4 FIRST AID MEASURES Inhalation: If user experiences breathing difficulty

Ethylbenzene 100-41-4 1 0-2 5 GHS02-GHS07-GHS08 H225-304-332-373 Ethyl 3-Ethoxypropionate 763-69-9 0 1-1 0 GHS06 H331 Methyl ethyl ketoxime 96-29-7 0 1-1 0 GHS05-GHS06 H302-312-317-318-331 4 First-Aid Measures FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open Get medical attention Do NOT allow rubbing of eyes or

100-41-4 ethylbenzene 1 64% 108-38-3 m-xylene 1 26% 95-63-6 1 2 4-trimethylbenzene 0 22% US 4 SECTION 4: FIRST AID MEASURES -aid measures (Contd of page 1) Wear protective gloves / eye protection / face protection Ground/bond container and receiving equipment Keep container tightly closed Use only non-sparking tools Take precautionary measures against static discharge Obtain

ENVIRONMENTAL HAZARDS Hazard to the Aquatic Environment (Acute) :Category1 Hazard to the Aquatic Environment (Chronic) :Category2 [Label elements] Pictogram : Signal Word :Danger Hazard Statement :Highly flammable liquid and vapour :Harmful if inhaled 1/6 202249E MITSUBISHI PENCIL CO LTD [Date of issue]:2015/06/11 :Causes skin irritation :Causes serious eye

Ethylbenzene 100-41 -4 0 1 0 3 4 First Aid Measures First aid procedures Move to fresh air If breathing is difficult give oxygen by qualified medical personnel only If breathing has stopped give artificial respiration Get medical attention Inhalation Remove contaminated clothing Wash off immediately with soap and plenty of water If irritation persists seek prompt medical attention

Benzene ethyl- Ethylbenzene Phenylethane 100-41-4 0 - 0 9% Benzene butyl- 1-Phenylbutane 104-51-8 0 - 0 8% Butane 2 2 3-trimethyl- Butane 2 3 3-trimethyl- 464-06-2 0 - 0 2% Pentane 2 3 4-trimethyl- 2 3 4-Trimethylpentane 565-75-3 0 - 0 15% * All concentrations are percent by weight Additional Information: This product has been assigned a CAS # of 68553-14-0 – Hydrocarbons C8

You will be assigned either toluene (methylbenzene) ethylbenzene or anisole (methoxybenzene) to acylate The reaction is one that comes out of your organic chemistry textbook so no procedure is available What variables should you consider when planning your reaction? The three starting materials that you want to try: Reactants Products anisole C 6H 5OCH 3 Liquid bp 154 4

1 Identification

Ethylbenzene Revision Date 17-Jan-2018 Autoignition Temperature 432 C / 810 F Decomposition Temperature No information available Viscosity No information available Molecular Formula C8 H10 Molecular Weight 106 17 10 Stability and reactivity Reactive Hazard None known based on information available Stability Stable under normal conditions Conditions to Avoid Incompatible products

Ethylbenzene Index REACh No 601-023-00-4 5 - 10 Flam Liq 2 Acute Tox 4 STOT RE 2 Asp Tox 1 H225 H332 H373 01-2119489370-35 H304 96-29-7 202-496-6 2-Butanone oxime Index REACh No 616-014-00-0 0 1 - 1 Carc 2 Acute Tox 4 Eye Dam 1 Skin Sens 1 H351 H312 H318 H317 01-2119539477-28 919-30-2 213-048-4 3-aminopropyltriethoxysilane Index REACh No 612-108-00-0

ENVIRONMENTAL HAZARDS WATER: N/A SECTION XV - REGULATORY INFORMATION TSCA STATUS: All Chemicals are listed or exempt CERCLA (COMPREHENSIVE RESPONSE COMPENSATION AND LIABILITY ACT): Xylenes (1330-20-7) Reportable Quantity = 100 lbs Ethylbenzene (100-41-4): RQ 1000lbs SARA 311/312 HAZARD CATEGORIES: Fire Hazard

2 HAZARDS IDENTIFICATION GHS Signal Word: DANGER GHS Hazard Pictograms: GHS Classifications: Physical Flammable Liquids 4 Health Skin corrosion/irritation 1 C Health Specific target organ toxicity - Single exposure 3 Health Carcinogenicity 2 Health Aspiration hazard 1 GHS Precautionary Statements: P210 - Keep away from heat/sparks/open flames/hot surfaces No

ENVIRONMENTAL HAZARDS Hazard to the Aquatic Environment (Acute) :Category1 Hazard to the Aquatic Environment (Chronic) :Category2 [Label elements] Pictogram : Signal Word :Danger Hazard Statement :Highly flammable liquid and vapour :Harmful if inhaled 1/6 202249E MITSUBISHI PENCIL CO LTD [Date of issue]:2015/06/11 :Causes skin irritation :Causes serious eye

100-41-4 ethylbenzene 1 64% 108-38-3 m-xylene 1 26% 95-63-6 1 2 4-trimethylbenzene 0 22% US 4 SECTION 4: FIRST AID MEASURES -aid measures (Contd of page 1) Wear protective gloves / eye protection / face protection Ground/bond container and receiving equipment Keep container tightly closed Use only non-sparking tools Take precautionary measures against static discharge Obtain

Ethylbenzene 8 9 100-41-4 Dimethyl Carbonate 8 6 616-38-6 Butane 6 4 106-97-8 Talc 5 38 14807-96-6 Iron Oxide 2 64 1309-37-1 2-Methyl-1-propanol 1 51 78-83-1 Lt Aliphatic Hydrocarbon Solvent 1 13 64742-89-8 Light Aliphatic Hydrocarbon Solvent 1 13 64742-49-0 Light Aliphatic Hydrocarbon Solvent 1 08 68410-97-9 Xylene mixed isomers 0 36 1330-20-7 Titanium Dioxide 0 24 13463-67-7 Heptane

ethylbenzene: Durability: CA Priority Pollutants IARC Carcinogens CA Prop 65 US EPA PBTs CA TACs ATSDR Neurotoxicants CA MCLs CA Non-Cancer Hazards: 2634-33-5: 1 2-benzisothiazoline-3-one: Preservative: None: 2682-20-4: 2-methyl-4-isothiazolin-3-one: Preservative: None: 67-63-0: isopropanol: Solvent: CA Non-Cancer Hazards US EPA PBTs

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure to xylene in laboratory animals has been associated with liver abnormalities kidney lung spleen eye and blood damage as well as reproductive disorders Effects in humans due to chronic overexposure have included liver cardiac abnormalities and nervous system damage IARC lists Ethylbenzene as a possible human

Ethylbenzene Index REACh No 601-023-00-4 5 - 10 Flam Liq 2 Acute Tox 4 STOT RE 2 Asp Tox 1 H225 H332 H373 01-2119489370-35 H304 96-29-7 202-496-6 2-Butanone oxime Index REACh No 616-014-00-0 0 1 - 1 Carc 2 Acute Tox 4 Eye Dam 1 Skin Sens 1 H351 H312 H318 H317 01-2119539477-28 919-30-2 213-048-4 3-aminopropyltriethoxysilane Index REACh No 612-108-00-0

ENVIRONMENTAL HAZARDS Hazard to the Aquatic Environment (Acute) :Category1 Hazard to the Aquatic Environment (Chronic) :Category2 [Label elements] Pictogram : Signal Word :Danger Hazard Statement :Highly flammable liquid and vapour :Harmful if inhaled 1/6 202249E MITSUBISHI PENCIL CO LTD [Date of issue]:2015/06/11 :Causes skin irritation :Causes serious eye

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